Magnetic circuit and method of applying magnetic field

ABSTRACT

In a magnetic circuit for providing magnetic anisotropy in the in-plane radial direction of a soft magnetic under layer, magnets for perpendicular magnetization are respectively provide on the north and south poles of a magnet for horizontal magnetization. When magnetic circuits configured thus are stacked in a plurality of stages, a magnetic field (air-gap magnetic field) formed in a gap between the magnetic circuits is superimposed by magnetic fields from the magnets for perpendicular magnetization as well as a magnetic field from the magnet for horizontal magnetization (in-plane magnetization). The pole faces of the magnets for perpendicular magnetization are disposed closer to the gap between the magnetic circuits, so that a stronger magnetic field can be formed in the gap.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to a magnetic circuit and, moreparticularly, the present invention relates to a magnetic circuitsuitably used for magnetic field heat treatment of a magnetic recordingmedium substrate and so on and a method of applying a magnetic field bymeans of the magnetic circuit.

2. Description of the Related Art

In the technical field of information recording, hard disk drives actingas means for magnetically reading and writing information includingcharacters, images, and music have become necessary as primary externalrecorders or internal recording means of electronic equipment such aspersonal computers. Such hard disk drives include hard disks serving asmagnetic recording media. For hard disks, a so-called “in-plane magneticrecording method (longitudinal magnetic recording method)” is availablein which magnetic information is longitudinally written in the plane ofa disk and “a perpendicular magnetic recording method” is available inwhich magnetic information is perpendicularly written in the plane of adisk.

FIG. 1 is a sectional view schematically showing a typical laminatedstructure of a hard disk of the longitudinal magnetic recording method.A non-magnetic Cr base layer 2 formed by a sputtering method, a magneticrecording layer 3, and a carbon layer 4 serving as a protective film aresequentially stacked on a non-magnetic substrate 1, and a liquidlubricating layer 5 formed by applying a lubricant is formed on asurface of the carbon layer 4. The layers are about 20 nm in thicknessat the most and are generally formed by a dry process such as amagnetron sputtering method (for example, see Japanese Patent Laid-OpenNo. 5-143972). The magnetic recording layer 3 is made of a Co alloyhaving uniaxial crystal magnetic anisotropy. The Co alloy includesCoCrTa and CoCrPt alloys. The crystal grains of the Co alloy arehorizontally magnetized relative to a surface of the disk to recordinformation.

However, in the longitudinal magnetic recording method, an increase inrecording density has been regarded as being limited because of thefollowing problems: when each recording region (magnetic domain) isreduced in size to increase a recording density, the north poles andsouth poles of adjacent magnetic domains repel each other and result incancellation of magnetization, so that for a high recording density, itis necessary to reduce the thickness of the magnetic recording layer andreduce the crystal grains in size, and finer crystal grains (smallervolumes) cause a phenomenon such as “thermal fluctuations” in which themagnetization direction of the crystal grains is disturbed by thermalenergy and data is deleted.

In response to these problems, the “perpendicular magnetic recordingmethod” has been studied. In this recording method, a magnetic recordinglayer is magnetized perpendicularly to a surface of a disk. Thus thenorth poles and the south poles are alternately combined and placed in abit arrangement and the north poles and south poles of magnetic domainsare adjacent to each other with enhanced magnetization. As a result,there is just a small number of self-demagnetizing fields (demagnetizingfields) in a bit and thus the magnetization (magnetic recording) is morestabilized. When the magnetization direction is recorded in theperpendicular direction, it is not necessary to significantly reduce thethickness of the magnetic recording layer. For this reason, even whenthe recording region is reduced in size in the horizontal direction, therecording layer is increased in thickness and the crystal grains areincreased in size in the perpendicular direction, so that the overallcrystal grains are increased in volume and the influence of “thermalfluctuations” can be reduced. Thus the perpendicular magnetic recordingmethod is expected as a method for achieving super high densityrecording.

FIG. 2 is a sectional view schematically showing a basic layeredstructure of a hard disk acting as a “perpendicular two-layer magneticrecording medium” in which a recording layer for perpendicular magneticrecording is provided on a soft magnetic under layer (SUL). A softmagnetic under layer (SUL) 12, a magnetic recording layer 13, aprotective layer 14, and a lubricating layer 15 are sequentially stackedon a non-magnetic substrate 11.

In this structure, the soft magnetic under layer 12 effectively acts toincrease a writing magnetic field and reduce the demagnetizing field ofthe magnetic recording layer 13. Permalloy, CoZrNb amorphous, and so onare typically used for the soft magnetic under layer 12. For themagnetic recording layer 13, a CoCrPt alloy, a PtCo film, a PtFe film,or a SmCo amorphous film or the like is used.

As shown in FIG. 2, in a hard disk of the perpendicular two-layermagnetic recording method, the soft magnetic under layer 12 is providedas the base of the magnetic recording layer 13. The soft magnetic underlayer 12 has a magnetic property of “soft magnetism” and has a thicknessof about 100 nm to 500 nm. The soft magnetic under layer 12 is providedto increase a writing magnetic field and reduce the demagnetizing fieldof the magnetic recording film. Further, the soft magnetic under layer12 acts as a path of a magnetic flux from the magnetic recording layer13 and a path of a writing magnetic flux from a recording head. In otherwords, the soft magnetic under layer 12 plays the same role as an ironyoke provided in a permanent magnet magnetic circuit. Thus in order toavoid magnetic saturation during writing, the thickness of the softmagnetic under layer 12 has to be set larger than that of the magneticrecording layer 13.

In view of the multilayer configuration, the soft magnetic under layer12 corresponds to the non-magnetic Cr base layer 2 provided in the harddisk of the longitudinal magnetic recording method shown in FIG. 1.However, the soft magnetic under layer 12 is not formed as easily as theCr base layer 2.

As described above, in the hard disk of the longitudinal magneticrecording method, each layer is about 20 nm in thickness at the most andis formed by a dry process (mainly by magnetron sputtering, see JapanesePatent Laid-Open No. 5-143972). Also for perpendicular two-layerrecording media, various methods have been studied to form the magneticrecording layer 13 and the soft magnetic under layer 12 by a dryprocess.

However, when the soft magnetic under layer 12 is formed by the dryprocess, a sputtering target has to be a ferromagnetic material havingstrong saturation magnetization and the soft magnetic under layer 12 hasto be 100 nm or larger in thickness. For these reasons, perpendiculartwo-layer recording media have serious problems about mass productionand productivity in consideration of the evenness of the film thicknessand composition, the life of the target, the stability of the process,and the low deposition rate above all.

For this reason, attempts to apply a metal film on the non-magneticsubstrate 11 by a plating method and use the metal film as the softmagnetic under layer 12 have been studied. In the plating method, thethickness of the metal film can be easily increased and can be polished.

FIG. 3 is an explanatory drawing showing a structural example of aperpendicular two-layer recording medium in which the soft magneticunder layer 12 is formed by plating. In this laminated structure,between the non-magnetic substrate 11 and the soft magnetic under layer12, a nucleation film 16 for obtaining adhesion to the substrate isformed by plating.

Incidentally, a number of magnetic domains magnetized in a specificdirection are prone to appear in the plane of a soft magnetic film anddomain walls appear on the interfaces of the magnetic domains. When thesoft magnetic film having such domain walls is used as a soft magneticunder layer for the perpendicular two-layer magnetic recording medium, aleakage magnetic field generated from the domain walls causes isolatedpulse noise called spike noise or micro-spike noise, so that the signalreproduction property may be seriously deteriorated. As a solution tothis problem, it is effective to make the soft magnetic film anisotropicin the in-plane radial direction serving as the easy axis ofmagnetization or in the in-plane circumferential direction.

FIG. 4 is an explanatory drawing of “magnetic anisotropy”. Ananisotropic magnetic field (H_(k)) is provided as a difference (δH)between a magnetization saturation magnetic field strength in thein-plane radial direction and a magnetization saturation magnetic fieldstrength in the in-plane circumferential direction. When δH is positive,the in-plane radial direction is the magnetization direction (anisotropydirection). When δH is negative, the in-plane circumferential directionis the magnetization direction (anisotropy direction). In this case, thenumeric value of magnetic anisotropy is represented as an absolutevalue.

When the soft magnetic film is formed by a dry process (for example, asputtering method), the soft magnetic film is provided with magneticanisotropy in the in-plane radial direction by applying a radialmagnetic field to the substrate during sputtering. When the softmagnetic film is formed by a wet process (for example, a platingmethod), the soft magnetic film can be provided with magnetic anisotropyin the in-plane circumferential direction by forming the soft magneticfilm while applying a magnetic field in one direction to the substrateand rotating the substrate during plating. Such magnetic anisotropy issubstantially axially symmetric with respect to the axis of thesubstrate and may be provided in either of the in-plane radial andcircumferential directions according to the simulation results of amagnetic recording process.

However, in both of the dry and wet processes, it is not easy tosimultaneously form a soft magnetic film with excellent filmcharacteristics and provide the film with magnetic anisotropy havinghigh axial symmetry. Thus a method for simultaneously achieving suchexcellent film characteristics and magnetic anisotropy is desired.

As an effective means of providing magnetic anisotropy, a technique ofheat-treating a soft magnetic substance in a magnetic field isavailable. For example, in a fabrication process of a GMR head, heattreatment is performed in a strong magnetic field exceeding 1 tesla (T)to orient a pin layer and a free layer, so that magnetic anisotropy isprovided in the direction of the magnetic field.

Further, it is known that in an audio-visual magnetic head, noise can bereduced by performing heat treatment in a rotating magnetic field (oneof a magnetic field device and the head is rotated) to obtain magneticisotropy.

However, in such a heat treatment process, it is necessary to form aheat treatment furnace including a non-magnetic component and generate amagnetic field in one direction in the heat treatment furnace. Thus amagnetic field generator tends to be large in size and require externalinstallation and the heat treatment furnace tends to have a complicatedconfiguration.

It can be said that a magnetic field heat treatment method for providinga soft magnetic substance with magnetic anisotropy or isotropy is anestablished technique. However, it is not easy to provide the softmagnetic under layer of the perpendicular two-layer recording mediumwith axially symmetric magnetic anisotropy in the in-plane radialdirection and the in-plane circumferential direction through magneticfield heat treatment. This is because in the configuration for applyinga magnetic field from the outside of the heat treatment furnace, it isdifficult to form a magnetic field in the in-plane radial direction orthe in-plane circumferential direction of the substrate disposed in thefurnace.

A magnetic field in the in-plane radial direction can be relativelyeasily formed with coils having the same poles facing each other.However, a region enabling a diverging magnetic field in the in-planeradial direction suitably for obtaining magnetic anisotropy is small.Further, a strong magnetic field is hard to obtain.

Under these constraints, soft magnetic under layers have not beenprovided with axially symmetric magnetic anisotropy through magneticfield heat treatment.

SUMMARY OF THE INVENTION

The present invention is designed in view of these problems. An objectof the present invention is to provide a permanent magnet magneticcircuit which is suitable for providing a soft magnetic substance(particularly, a soft magnetic under layer (SUL film) for aperpendicular two-layer magnetic recording medium) with axiallysymmetric magnetic anisotropy through magnetic field heat treatment andis capable of generating a stronger magnetic field, and provide a methodof applying a magnetic field by using the permanent magnet magneticcircuit.

In order to solve the above problems, a magnetic circuit of the presentinvention for storing a sample in a gap formed between a plurality ofmagnetic field application parts opposed to each other in parallel andapplying a magnetic field to the sample, wherein each of the magneticfield application parts is configured by combining a plurality ofpermanent magnet segments, the permanent magnet segments include a firstpermanent magnet horizontally magnetized in parallel with the opposedsurface of the magnet field application part, a second permanent magnetmagnetized perpendicularly to the opposed surface of the magnetic fieldapplication part, the second permanent magnet being provided on thenorth pole of the first permanent magnet, and a third permanent magnetperpendicularly magnetized in the opposite direction from the secondmagnet, the third permanent magnet being provided on the south pole ofthe first permanent magnet.

Preferably, the magnetic field application parts are configured like aring around the virtual axis with a combination of the plurality offirst to third permanent magnets, the first permanent magnet is disposedsuch that the first permanent magnet is magnetized in a direction to thevirtual axis or perpendicularly to the direction to the virtual axis.

When the first permanent magnet is disposed such that the firstpermanent magnet is magnetized perpendicularly to the direction to thevirtual axis, the first permanent magnet is preferably magnetized in adirection different from the magnetization direction of another firstpermanent magnet by about 90°.

In the magnetic circuit of the present invention, the magnet is, forexample, a 2-17 SmCo magnet having a coercive force of at least 20 kOeand the gap is, for example, 50 mm to 100 mm.

A method of applying a magnetic field according to the present inventionby using the magnetic circuit of the present invention, the methodincluding the steps of: storing a disk-like sample in the gap of themagnetic circuit; providing the disk-like sample and the magneticcircuit with a relative rotational speed in a state in which the axis ofthe disk-like sample is aligned with the virtual axis of the magneticcircuit; and applying a magnetic field in one of the in-planecircumferential direction and the in-plane radial direction over thedisk-like sample.

According to the present invention, in addition to a side of themagnetic field application part (the pole side of the magnet), themagnets having pole faces on the magnet gap surfaces are used forapplying a magnetic field. Thus it is possible to form a strong magneticfield in a gap between the magnetic field application parts (magnets),thereby effectively performing magnetic field thermal treatment on themagnetic sample.

Therefore, according to the magnetic circuit of the present invention,it is possible to set a large gap and increase the number of magneticsamples treatable in magnetic field thermal treatment at a time, so thata compact magnetic circuit can be designed.

BRIEF DESCRIPTION OF THE DRAWINGS

Other objects, features and advantages of the present invention willbecome more apparent from the following detail description when read inconjunction with the accompanying drawings in which:

FIG. 1 is a sectional view schematically showing a typical laminatedstructure of a hard disk of a longitudinal magnetic recording method;

FIG. 2 is sectional view schematically showing a basic layered structureof a hard disk acting as a perpendicular two-layer magnetic recordingmedium;

FIG. 3 is an explanatory drawing showing a structural example of aperpendicular two-layer recording medium in which a soft magnetic underlayer is formed by plating;

FIG. 4 is an explanatory drawing of “magnetic anisotropy”;

FIGS. 5A, 5B, and 5C are schematic diagrams showing the states of themagnetic fields of anisotropic magnets;

FIGS. 6A and 6B are explanatory drawings of the states of magneticfluxes of a radial magnetic field (FIG. 6A) and a circumferentialmagnetic field (FIG. 6B);

FIGS. 7A and 7B are explanatory drawings of structural examples of amagnetic circuit made by the present inventors (FIG. 7A: a radialmagnetic field, FIG. 7B: a circumferential magnet circuit);

FIGS. 8A and 8B are explanatory drawings of structural examples of amagnetic circuit made by the present inventors (FIG. 8A: a radialmagnetic field, FIG. 8B: a circumferential magnet circuit);

FIGS. 9A and 9B are explanatory drawings showing a first structuralexample of a magnetic circuit according to the present invention inwhich magnetic anisotropy is provided in the in-plane radial directionof a soft magnetic under layer formed on a substrate;

FIG. 9A is a top view of the magnetic circuit;

FIG. 9B is a sectional view taken along line b-b′ of FIG. 9A;

FIGS. 10A and 10B are explanatory drawings showing a second structuralexample of the magnetic circuit according to the present invention inwhich magnetic anisotropy is provided in the in-plane circumferentialdirection of a soft magnetic under layer formed on a substrate;

FIG. 10A is a top view of the magnetic circuit; and

FIG. 10B is a sectional view taken along line b-b′ of FIG. 10A.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

Exemplary embodiments for implementing the present invention will bespecifically described below with reference to the accompanyingdrawings.

The present inventors have devoted themselves to conduct studies on amethod of generating a magnetic field and have invented a permanentmagnetic circuit of the present invention by combining a plurality ofpermanent magnets in different magnetization directions. The permanentmagnet magnetic circuit can generate a stronger magnetic field than aconventional magnetic circuit at high temperatures. Further, the presentinventors have also invented a method of applying a magnetic field byusing the permanent magnetic circuit in a heat treatment furnace suchthat the magnetic field is substantially axially symmetric with respectto a magnetic substance to be treated.

First, the following will describe how the inventors have reached thepresent invention.

Sintered rare earth permanent magnets are generally anisotropic sinteredmagnets which are molded and sintered with C axes aligned in magneticfields.

FIGS. 5A, 5B and 5C are schematic diagrams showing the states of themagnetic fields of such anisotropic magnets. As shown in FIG. 5A, amagnetic flux emerges from the north pole face of a magnet 20 and entersthe south pole face of the magnet 20. The north and south poles arealways paired (dipole moment) and the amount of the emerging magneticflux and the amount of the entering magnetic flux are balanced with eachother. Unlike electric charge, magnetic charge cannot be separatelydrawn out. Thus a magnetic field distribution (including a direction)realized by permanent magnets is restricted. It is relatively easy togenerate a magnetic field in one direction facing a pole face through ayoke 21 which is a magnetic substance (FIG. 5B) and it is also easy togenerate a curved magnetic field distribution between poles (FIG. 5C).

On the other hand, it is difficult to realize a magnetic fielddistribution including a radial magnetic field radiating in one planeand a circumferential magnetic field generated like a ring.

FIGS. 6A and 6B are explanatory drawings showing the states of themagnetic fluxes of the radial and circumferential magnetic fields. Theradial magnetic field (FIG. 6A) is difficult to form because it isdifficult to balance the amounts of magnetic charge on the inner sideand the outer side. Further, the circumferential magnetic field (FIG.6B) is difficult to form because even in the presence of anisotropy inthe circumferential direction of a ring-shaped magnet, the flow of amagnetic flux is basically closed in the magnet and hardly leaks out ofthe magnet due to the absence of an exit of the magnetic flux.

The present inventors mounted permanent magnet magnetic circuits in aheat treatment furnace and performed magnetic field heat treatment in astate in which the magnetic circuits and an object to be treated are setat the same temperature.

FIGS. 7A and 7B are explanatory drawings showing structural examples ofa magnetic circuit having been studied in these attempts. In FIGS. 7Aand 7B, reference numerals 20A and 20B denote magnetic field applicationparts, each being made up of a relatively small permanent magnetmagnetic circuit. The magnetization directions (that is, the magneticfield directions) are indicated by arrows.

The magnetic field application part 20A shown in FIG. 7A generates amagnetic field in the radial direction of a soft magnetic under layer 12on a non-magnetic substrate. The soft magnetic under layer 12 rotatesabout an axis (C) of the substrate, so that the magnetic field isapplied over the substrate in terms of time average. The magnetic fieldapplication part 20B shown in FIG. 7B generates a magnetic field in thecircumferential direction of a soft magnetic under layer 12. The softmagnetic under layer 12 rotates about an axis (C) of the substrate, sothat the magnetic field is similarly applied over the substrate in termsof time average.

When a magnetic field is applied, as shown in FIG. 7A, using themagnetic field application part 20A for generating a magnetic field inthe radial direction of the soft magnetic under layer 12, magneticanisotropy is provided for the magnetization curve of the radialdirection in the plane of the substrate. When a magnetic field isapplied, as shown in FIG. 7B, using the magnetic field application part20B for generating a magnetic field in the circumferential direction ofthe soft magnetic under layer 12, magnetic anisotropy is provided forthe magnetization curve of the circumferential direction in the plane ofthe substrate.

Through these studies, the present inventors confirmed that axiallysymmetric magnetic anisotropy can be provided for a magnetic substanceby rotating the magnetic substance while applying a magnetic field to apart or the whole of the magnetic substance serving as an object to betreated.

For example, in the magnetic circuit in FIG. 7A or FIG. 7B, between themagnet serving as the magnetic field application part (20A, 20B) and thesoft magnetic under layer 12 serving as an object to be treated, amagnetic field can be generated substantially in the opposite directionfrom the magnetization direction of the magnet. Assuming that the magnetis a rare-earth magnet, a magnetic flux leaking from a side of themagnet is almost negligible. Thus the direction and strength of anair-gap magnetic flux can be easily controlled.

Further, the directions of the application of a magnetic field to theobject to be treated can be selected by switching the two kinds ofmagnetic circuit shown in FIGS. 7A and 7B. For example, in the case of acircular object to be treated as shown in FIGS. 7A and 7B, the magneticfield application part 20A of FIG. 7A can generate a magnetic field inthe in-plane radial direction and the magnetic field application part20B of FIG. 7B can generate a magnetic field in the in-planecircumferential direction. Further, when a magnetic field is to beapplied in the intermediate direction of the in-plane radial directionand the in-plane circumferential direction, the magnetization directionof the magnet (20A, 20B) is preferably set in the intermediatedirection.

Particularly, by stacking these magnetic circuits in a plurality ofstages and inserting a plurality of objects to be treated into gapsbetween the magnetic circuits to treat the objects in a collectivemanner, magnetic anisotropy can be provided for a plurality of magneticsubstances through one treatment at a time.

However, as a result of the studies, the inventors concluded that in themagnetic circuits configured thus, even if a rare-earth magnet is usedfor the magnetic application part, it is difficult to sufficientlyincrease the strength of a magnetic field in the gap area. This isbecause the magnetic field is generated in the gap orthogonal to thepole face of the magnet.

The magnetic field strength of the order of kilogauss (kG) can be easilyobtained by setting a relatively narrow gap (e.g., not larger than 30mm) between the magnetic field application parts (magnets). However, inview of practical use, it is desired to generate a magnetic field with acontrolled direction and strength in a wider gap area (e.g., about 100mm) and treat a number of samples at the same time. Thus, in view ofpractical use, it is difficult to obtain a sufficient magnetic fieldstrength in the magnetic circuits configured as shown in FIGS. 7A and7B.

The inventors conducted studies to enable more effective magnetic fieldheat treatment by increasing the strength of a magnetic field generatedin a gap between magnetic field application parts (magnets) and toincrease the number of magnetic samples simultaneously treatable in onemagnetic field heat treatment by setting a large gap, in a magneticcircuit for providing a magnetic sample with magnetic anisotropy in thecircumferential direction or the radial direction. As a result, thepresent inventors have reached the present invention.

FIGS. 8A and 8B are explanatory drawings showing structural examples ofa magnetic circuit according to the present invention. The magneticcircuit of the present invention is improved from the above magneticcircuits described with reference to FIGS. 7A and 7B. In the basicdesign concept of the magnetic circuits of FIGS. 7A and 7B, only a sideof the magnetic field application part (the pole side of the magnet) isused for applying a magnetic field, whereas in the present invention,magnets having pole faces on magnet gap faces are also used to increasea magnetic field in a gap.

For example, in the magnet circuit for providing magnetic anisotropy inthe in-plane radial direction of a soft magnetic under layer 12 formedon a substrate, as shown in FIG. 8A, a magnetic field application part(magnet) 20Aa (having the north pole on the top surface in FIG. 8A) anda magnetic field application part 20Ab (having the south pole on the topsurface in FIG. 8A) are respectively provided on the south and northpoles of a magnetic field application part (magnet) 20A shown in FIG.7A.

When magnetic circuits configured thus are stacked in a plurality ofstages, a magnetic field (air-gap magnetic field) formed in a gapbetween the magnetic circuits is superimposed by magnetic fields fromthe magnets (20Aa and 20Ab) for perpendicular magnetization as well as amagnetic field from the magnet (20A) for horizontal magnetization(in-plane magnetization). The pole faces of the magnets forperpendicular magnetization are disposed closer to the gap between themagnetic circuits, so that a stronger magnetic field can be formed inthe gap. Further, since the magnets (20Aa and 20Ab) for perpendicularmagnetization are disposed on the north pole and the south pole of themagnet (20A) for horizontal magnetization, the magnetic fieldsuperimposing effect is further enhanced as compared with the case wherea magnet for perpendicular magnetization is provided on only one of thepoles.

In the configuration of the magnetic field application parts (20A, 20Aaand 20Ab) shown in FIG. 8A, the magnetization directions of the magnet20A and the magnets 20Aa and 20Ab are different from each other by 90°.The magnetization direction may gradually change by an angle of 90° orless.

Moreover, in the magnet circuit for providing magnetic anisotropy in thein-plane circumferential direction of a soft magnetic under layer 12formed on a substrate, as shown in FIG. 8B, a magnetic field applicationpart (magnet) 20Ba (having the north pole on the top surface in FIG. 8B)and a magnetic field application part 20Bb (having the south pole on thetop surface in FIG. 8B) are respectively provided on the south and northpoles of a magnetic field application part (magnet) 20B shown in FIG.7B.

When magnetic circuits configured thus are stacked in a plurality ofstages, a magnetic field (air-gap magnetic field) formed in a gapbetween the magnetic circuits is superimposed by magnetic fields fromthe magnets (20Ba and 20Bb) for perpendicular magnetization as well as amagnetic field from the magnet (20B) for horizontal magnetization(in-plane magnetization) and the pole faces of the magnets forperpendicular magnetization are disposed closer to the gap between themagnetic circuits, so that a stronger magnetic field can be formed inthe gap. Further, since the magnets (20Ba and 20Bb) for perpendicularmagnetization are disposed on the north pole and the south pole of themagnet (20B) for horizontal magnetization, the magnetic fieldsuperimposing effect is further enhanced as compared with the case wherea magnet for perpendicular magnetization is provided on only one of thepoles.

In the configuration of the magnetic field application parts (20B, 20Baand 20Bb) shown in FIG. 8B, the magnetization directions of the magnet20B and the magnets 20Ba and 20Bb are different from each other by 90°.The magnetization direction may gradually change by an angle of 90° orless.

The magnetic fields generated by the magnetic circuits of FIGS. 8A and8B cannot be axially symmetrically applied to the object to be treated.Thus at least one of the magnetic circuit and the object to be treatedis rotated to have a relative rotational speed, so that an axiallysymmetric magnetic field is substantially applied to the object to betreated. In FIGS. 8A and 8B, the substrate serving as an object to betreated is rotated.

A magnetic field for providing magnetic anisotropy is applied thus toperform magnetic field heat treatment and thus the substrate is rotatedalong with the heat treatment. Normally, the magnetic field heattreatment is slowly performed for 5 minutes to several hours. Therefore,when the relative rotational speed is 5 rpm to 500 rpm, an appliedmagnetic field can be regarded as an axially symmetric magnetic field.Axial symmetry may not be obtained in terms of time average when therelative rotational speed is less than 5 rpm. A rotation mechanism maybe complicated when the relative rotational speed exceeds 500 rpm. Thelower limit of the relative rotational speed is preferably 10 rpm andthe upper limit of the relative rotational speed is preferably 150 rpm.

Since the magnetic circuit of the present invention is provided in aheat treatment furnace, one of the important challenges is to providethe magnetic circuit with thermal resistance. Generally, magnetic fieldheat treatment is performed at 150° C. to 300° C. and thus the magneticcircuit should not be thermally demagnetized in this temperature range.

When a NdFeB sintered magnet is used as the magnetic application part toprovide the magnetic circuit of the present invention with heatresistance, it is preferable that the magnet has a coercive force of atleast 20 kilooersteds (kOe). A coercive force of 30 kilooersteds (kOe)or larger is more preferable.

On the other hand, when a 2-17 type SmCo magnet is used, it ispreferable to have a coercive force of at least 10 kOe. A coercive forceof 20 kOe or larger is more preferable. The 2-17 type SmCo magnet haslower saturation magnetization than the NdFeB magnet but the reversibletemperature coefficient of the coercive force is about one third that ofthe NdFeB magnet. Thus the 2-17 type SmCo magnet is suitable formagnetic field heat treatment at 200° C. or higher.

The magnetic circuit of the present invention can be also used at atemperature below 150° C. Assuming that the magnetic circuit is used athigh temperatures of 150° C. or higher, it is not preferable to use anadhesive when fixing the magnets. Even with a heat-resistant epoxyadhesive, it is difficult to keep the original adhesion over the longterm at high temperatures exceeding 150° C. Further, volatile gasgenerated from an adhesive may adversely affect an untreated sample athigh temperatures. Therefore, the way the magnets are fixed isimportant.

A rare-earth permanent magnet has an intermetallic compound as a mainphase, is highly brittle, and is hard to be tapped. Thus a rare-earthpermanent magnet cannot be substantially screwed and is preferably fixedin a mechanical manner. “Fixed in a mechanical manner” means that in thepermanent magnet magnetic circuit made up of two or more rare-earthpermanent magnets, the spacing of the sides of the magnets and thepositional relationship between the magnetization directions are keptwithout using an adhesive or directly using a screw.

To be specific, effective methods include a method of forming a step ona part of a magnet to apply a pressure and a method of forming a taperedportion (regardless of a non-magnetic material and a magnetic material)on a magnet and fixing the tapered portion on a support plate via anon-magnetic bolt.

Although a magnetic surface may be bare, it is more desirable to apply ametallic coating on the magnetic surface. Since a rare-earth magnet isgenerally brittle, an external force directly applied to a surface ofthe rare-earth magnet may cause a crack or a chip. In order to prevent acrack and a chip, it is effective to apply a coating of a ductile metalaccording to a technique such as Ni plating and Al ion plating.

The shape of the magnet used for the magnetic circuit is not limited toa specific shape. It is preferable that the shape of the magnet allowsthe magnetic circuit of a single stage to be configured as a ring-shapedmagnetic circuit and allows the single-stage magnetic circuits to bestacked in at least two stages with gaps formed between the magneticcircuits. A Halbach configuration is preferable in which a magneticfield can be generated in the in-plane radial direction or the in-planecircumferential direction by the magnetization directions of magneticfield application parts (magnets) provided on each magnetic circuit of asingle stage.

Particularly in the case of a magnetic circuit for in-planecircumferential magnetization, it is preferable to dispose magnets so asto rotate and change the magnetization direction by 90° at a time.Although the thickness of the magnet is not particularly limited, it ispreferable to include a segment magnet treated to have a thickness of 5mm to 100 mm.

FIGS. 9A and 9B are explanatory drawings showing a first structuralexample of the magnetic circuit according to the present invention. Inthis magnetic circuit, the magnetization directions of magnets areselected to provide magnetic anisotropy in the in-plane radial directionof a soft magnetic under layer formed on a substrate. FIG. 9A is a topview of the magnetic circuit and FIG. 9B is a sectional view taken alongline b-b′ of FIG. 9A.

The magnetic circuit of a single stage is configured by combining aplurality of (five in FIG. 8A) magnetic field application parts 20, eachincluding the three magnets (the magnet (20A) for horizontalmagnetization and the magnets (20Aa and 20Ab) for perpendicularmagnetization) described with reference to FIG. 8A. The single-stagemagnetic circuits are stacked in five stages, a plurality of substrateshaving soft magnetic under layers 12 formed thereon are set in a gapformed between the stages, and magnetic fields are applied to thesubstrates.

The virtual center of the magnetic circuit and the axis of the substrateare substantially aligned with each other. The substrate can be rotatedabout an axis (C) of the substrate by a rotation mechanism (not shown)and a magnetic field is applied over the soft magnetic under layer bythe rotation.

FIGS. 9A and 9B illustrate the magnets for generating magnetic fields inthe radial direction of the soft magnetic under layer. When a magneticfield is applied using a magnet for generating a magnetic field in thecircumferential direction of the soft magnetic under layer, magneticanisotropy is provided for a magnetization curve of the circumferentialdirection in the plane of the soft magnetic under layer.

FIGS. 10A and 10B show a structural example of the magnetic circuit inwhich the magnetization directions of magnets are selected to providemagnetic anisotropy in the in-plane circumferential direction of a softmagnetic under layer formed on a substrate. FIG. 10A is a top view ofthe magnetic circuit and FIG. 10B is a sectional view taken along lineb-b′ of FIG. 10A.

In the magnetic circuit of FIGS. 10A and 10B, the magnets are disposedsuch that the magnetization direction rotates and changes by 90° at atime. In this case, the magnetic field direction periodically changesalong the in-plane circumferential direction of the substrate. Even ifthe magnetic field direction changes by 180°, the direction of themagnetic anisotropy of the soft magnetic under layer (SUL film) is notaffected as long as the angle of the magnetic field does not change.Thus no problems occur.

In both of the magnetic circuits of FIGS. 9A and 9B and FIGS. 10A and10B, the gap between the magnets is set at about 30 mm to 200 mm,preferably at 50 mm to 100 mm. Further, In both of the magnetic circuitsof FIGS. 9A and 9B and FIGS. 10A and 10B, a “notched portion” is formedby removing a part of the magnets combined like a ring. Such a “notchedportion” makes it possible to insert a supporting rod into the centralhole of the substrate to be treated and set the supporting rod inalignment with the virtual axis of the magnetic circuit, therebyimproving workability.

The magnetic circuit of the present invention is used in, for example, afabrication process of a perpendicular magnetic recording medium. Asuitable object to be treated includes a soft magnetic under layerprovided on a substrate. As described above, a material of the substrateincludes, for example, a Si single crystal, a crystal tempered glass, anamorphous tempered glass, and aluminum. A soft magnetic materialcontained in the soft magnetic under layer includes, for example, atleast one material selected from Ni, Co and Fe. Normally, the softmagnetic material contained in the soft magnetic under layer has acoercive force of 20 Oe or less, preferably 0.1 Oe to 10 Oe.

The soft magnetic under layer may be formed according to either the dryprocess such as a sputtering method or the wet process such as a platingmethod. The soft magnetic under layer is preferably 10 nm to 1000 nm inthickness. The lower limit of the thickness is preferably 50 nm and theupper limit of the thickness is preferably 500 nm.

EXAMPLE

Magnetic circuits configured as shown in FIGS. 9A and 9B or FIGS. 10Aand 10B were produced using a 2-17 type SmCo magnet of H_(cj)=25 kOe atB_(r)=11 kG and a Nd2Fe14B magnet of H_(cj)=30 kOe at B_(r)=12.5 kG. Themagnetic field application surfaces of these magnetic circuits were eachconfigured by combining a plurality of sets of magnets (the magnets 20in FIGS. 9A and 9B and the magnets 20B, 20Ba and 20Bb in FIGS. 10A and10B).

Further, in order to prevent chips, electric nickel plating (about 10 μmin thickness) was performed on the surfaces of the magnets 20. Themagnets 20 were 15 mm to 25 mm in thickness and a gap between the magnetsurfaces was 50 mm to 100 mm. Moreover, the magnets were fixed andprevented from coming out of the circuit by tapering the magnets. Thefive magnetic application surfaces were stacked with four gaps.

Table 1 shows the measurement results of magnetic field strengths havingbeen measured at the center of the gap by a gauss meter and shows thedemagnetizing factors of the magnetic circuits after the magneticcircuits were heat-treated at high temperatures of 160° C. to 300° C.(kept for one hour). TABLE 1 Magnetic Magnet Field ExposureDemagnetizing Rare-earth Thickness Gap Strength Magnetic FieldTemperature Factor No Magnet mm mm kOe Direction ° C. % 1 NdFeB 15 501.45 Circumferential 160 1.8 Direction 2 NdFeB 20 70 0.98 RadialDirection 180 1.2 3 2-17SmCo 15 50 1.20 Radial Direction 200 0.40 42-17SmCo 15 50 1.25 Circumferential 230 0.85 Direction 5 2-17SmCo 20 701.10 Circumferential 250 1.0 Direction 6 2-17SmCo 30 100 0.75 RadialDirection 300 1.50

In all of the magnetic circuits, no large demagnetizing factors were notfound after the high-temperature heat treatment. Moreover, in all ofsamples 1 to 6, each having a gap of 50 mm or larger, an air-gapmagnetic field of 500 G or more was obtained.

A magnetic field was applied to a soft magnetic under layer by usingthese magnetic circuits. The soft magnetic under layer was provided forperpendicular magnetic recording and was obtained by sequentiallyplating a Ni film and a CoNiFeB film on a Si single crystal (100)(P-doped n-type substrate) having a diameter of 65 mm. The coerciveforce of the soft magnetic under layer was 3.00 Oe, which was apreferable soft magnetic property.

The substrates including the soft magnetic under layers wererespectively stored in the gaps between the magnetic circuits shown inTable 1, the axes of the substrates and the magnetic circuits werealigned with each other, and the substrates were subjected to magneticfield heat treatment in Ar inert gas for one hour while being rotated at80 rpm. The heat treatment temperatures are shown in Table 1.

After the samples were cooled, the magnetic properties of the softmagnetic under layers were measured. As a result, it was confirmed thatmagnetic anisotropy of about 15 Oe to 250 Oe was provided over thesubstrates in the in-plane radial direction or the in-planecircumferential direction according to the directions of the appliedmagnetic fields. Further, the magnetic anisotropy and symmetry aroundthe axes of the substrates were preferable. Therefore, it was confirmedthat even when a large gap was set between the magnets, an axiallysymmetric magnetic field was applied and the soft magnetic under layerscould be provided with sufficiently practical magnetic anisotropy in themagnetic circuits of the present invention.

According to the present invention, it is possible to provide a magneticcircuit making to possible to effectively perform magnetic field heattreatment on magnetic samples. Particularly, a permanent magnet magneticcircuit is provided which is suitable for providing a soft magneticsubstance (particularly, a soft magnetic under layer (SUL film) for aperpendicular two-layer magnetic recording medium) with axiallysymmetric magnetic anisotropy through magnetic field heat treatment andis capable of generating a strong magnetic field.

1. A magnetic circuit for storing a sample in a gap formed between aplurality of magnetic field application parts opposed to each other inparallel and applying a magnetic field to the sample, wherein each ofthe magnetic field application parts is configured by combining aplurality of permanent magnet segments, the permanent magnet segmentsinclude a first permanent magnet horizontally magnetized in parallelwith an opposed surface of the magnet field application part, a secondpermanent magnet magnetized perpendicularly to the opposed surface ofthe magnetic field application part, the second permanent magnet beingprovided on a north pole of the first permanent magnet, and a thirdpermanent magnet perpendicularly magnetized in an opposite directionfrom the second magnet, the third permanent magnet being provided on asouth pole of the first permanent magnet.
 2. A method of applying amagnetic field using the magnetic circuit according to claim 1, themethod comprising the steps of: storing a disk-like sample in the gap;providing the disk-like sample and the magnetic circuit with a relativerotational speed in a state in which an axis of the disk-like sample isaligned with a virtual axis of the magnetic circuit; and applying amagnetic field in one of an in-plane circumferential direction and anin-plane radial direction over the disk-like sample.
 3. The magneticcircuit according to claim 1, wherein the magnet is a 2-17 type SmComagnet having a coercive force of at least 20 kOe and the gap is 50 mmto 100 mm.
 4. A method of applying a magnetic field using the magneticcircuit according to claim 3, the method comprising the steps of:storing a disk-like sample in the gap; providing the disk-like sampleand the magnetic circuit with a relative rotational speed in a state inwhich an axis of the disk-like sample is aligned with a virtual axis ofthe magnetic circuit; and applying a magnetic field in one of anin-plane circumferential direction and an in-plane radial direction overthe disk-like sample.
 5. The magnetic circuit according to claim 1,wherein the magnetic field application parts are configured like a ringaround a virtual axis with a combination of the plurality of first tothird permanent magnets, the first permanent magnet is disposed suchthat the first permanent magnet is magnetized in a direction to thevirtual axis.
 6. A method of applying a magnetic field using themagnetic circuit according to claim 5, the method comprising the stepsof: storing a disk-like sample in the gap; providing the disk-likesample and the magnetic circuit with a relative rotational speed in astate in which an axis of the disk-like sample is aligned with a virtualaxis of the magnetic circuit; and applying a magnetic field in one of anin-plane circumferential direction and an in-plane radial direction overthe disk-like sample.
 7. The magnetic circuit according to claim 5,wherein the magnet is a 2-17 type SmCo magnet having a coercive force ofat least 20 kOe and the gap is 50 mm to 100 mm.
 8. A method of applyinga magnetic field using the magnetic circuit according to claim 7, themethod comprising the steps of: storing a disk-like sample in the gap;providing the disk-like sample and the magnetic circuit with a relativerotational speed in a state in which an axis of the disk-like sample isaligned with a virtual axis of the magnetic circuit; and applying amagnetic field in one of an in-plane circumferential direction and anin-plane radial direction over the disk-like sample.
 9. The magneticcircuit according to claim 1, wherein the magnetic field applicationparts are configured like a ring around a virtual axis with acombination of the plurality of first to third permanent magnets, thefirst permanent magnet is disposed such that the first permanent magnetis magnetized perpendicularly to a direction to the virtual axis.
 10. Amethod of applying a magnetic field using the magnetic circuit accordingto claim 9, the method comprising the steps of: storing a disk-likesample in the gap; providing the disk-like sample and the magneticcircuit with a relative rotational speed in a state in which an axis ofthe disk-like sample is aligned with a virtual axis of the magneticcircuit; and applying a magnetic field in one of an in-planecircumferential direction and an in-plane radial direction over thedisk-like sample.
 11. The magnetic circuit according to claim 9, whereinthe magnet is a 2-17 type SmCo magnet having a coercive force of atleast 20 kOe and the gap is 50 mm to 100 mm.
 12. A method of applying amagnetic field using the magnetic circuit according to claim 11, themethod comprising the steps of: storing a disk-like sample in the gap;providing the disk-like sample and the magnetic circuit with a relativerotational speed in a state in which an axis of the disk-like sample isaligned with a virtual axis of the magnetic circuit; and applying amagnetic field in one of an in-plane circumferential direction and anin-plane radial direction over the disk-like sample.
 13. The magneticcircuit according to claim 9, wherein the first permanent magnet ismagnetized in a direction different from a magnetization direction ofanother adjacent first permanent magnet by about 90°.
 14. A method ofapplying a magnetic field using the magnetic circuit according to claim13, the method comprising the steps of: storing a disk-like sample inthe gap; providing the disk-like sample and the magnetic circuit with arelative rotational speed in a state in which an axis of the disk-likesample is aligned with a virtual axis of the magnetic circuit; andapplying a magnetic field in one of an in-plane circumferentialdirection and an in-plane radial direction over the disk-like sample.15. The magnetic circuit according to claim 13, wherein the magnet is a2-17 type SmCo magnet having a coercive force of at least 20 kOe and thegap is 50 mm to 100 mm.
 16. A method of applying a magnetic field usingthe magnetic circuit according to claim 15, the method comprising thesteps of: storing a disk-like sample in the gap; providing the disk-likesample and the magnetic circuit with a relative rotational speed in astate in which an axis of the disk-like sample is aligned with a virtualaxis of the magnetic circuit; and applying a magnetic field in one of anin-plane circumferential direction and an in-plane radial direction overthe disk-like sample.